Chemical communications (Cambridge, England). 2002 May 21:(10):1102-3. doi: 10.1039/b201582j Q24.32024

Reversible skeletal substitution reactions involving group 13 heterophosphazenes

涉及第13族异磷杂氮化合物的可逆骨架取代反应翻译改进

Andrew R McWilliams¹, Eric Rivard, Alan J Lough, Ian Manners

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作者单位

¹ Department of Chemistry, University of Toronto, 80 St. George Street, Toronto, Ontario, Canada M5S 3H6.

DOI: 10.1039/b201582j PMID: 12122685

The cyclic boratophosphazene, N(PCl2NMe)2BCl2 1, reacts with two equivalents of AlMe3 to give the aluminatophosphazene heterocycle, N(PCl2NMe)2AlClMe 4. The unprecedented reverse skeletal substitution (Al for B) was accomplished by treating 4 with Ag[BF4] to form the fluorinated boratophosphazene N(PCl2NMe)2BF2 5.

Keywords：group 13 heterophosphazenes

关键词：可逆骨架取代; 第13族异磷氮杂烯